
Image of the traditional shape of the electron developed after 1830
The electron e−, or (β− in nuclear reactions) is a subatomic particle with a negative one elementary electric charge.[13] Electrons belong to the first generation of the lepton particle family,[14] and are generally thought to be elementary particles because they have no known components or substructure.[1]
The electron’s mass is approximately 1/1836 that of the proton.[15] Quantum mechanical properties of the electron include an intrinsic angular momentum (spin) of a half-integer value, expressed in units of the reduced Planck constant, ħ. Being fermions, no two electrons can occupy the same quantum state, per the Pauli exclusion principle.[14]
Like all elementary particles, electrons exhibit properties of both particles and waves: They can collide with other particles and can be diffracted like light. The wave properties of electrons are easier to observe with experiments than those of other particles like neutrons and protons because electrons have a lower mass and hence a longer de Broglie wavelength for a given energy.
In 1838, British natural philosopher Richard Laming first hypothesized the concept of an indivisible quantity of electric charge to explain the chemical properties of atoms.[3] Irish physicist George Johnstone Stoney named this charge “electron” in 1891, and J. J. Thomson and his team of British physicists identified it as a particle in 1897 during the cathode-ray tube experiment.[5]
The name “electron” was adopted for these particles by the scientific community, mainly due to the advocation by G. F. FitzGerald, J. Larmor, and H. A. Lorentz.[46]: 273 The term was originally coined by George Johnstone Stoney in 1891 as a tentative name for the basic unit of electrical charge (which had then yet to be discovered).[47][26]
The electron’s charge was more carefully measured by the American physicists Robert Millikan and Harvey Fletcher in their oil-drop experiment of 1909, the results of which were published in 1911. This experiment used an electric field to prevent a charged droplet of oil from falling as a result of gravity. This device could measure the electric charge from as few as 1–150 ions with an error margin of less than 0.3%.
Comparable experiments had been done earlier by Thomson’s team,[5] using clouds of charged water droplets generated by electrolysis, and in 1911 by Abram Ioffe, who independently obtained the same result as Millikan using charged microparticles of metals, then published his results in 1913.[48] However, oil drops were more stable than water drops because of their slower evaporation rate, and thus more suited to precise experimentation over longer periods of time.[49]
Atomic theory in early 19th century
By 1914, experiments by physicists Ernest Rutherford, Henry Moseley, James Franck and Gustav Hertz had largely established the structure of an atom as a dense nucleus of positive charge surrounded by lower-mass electrons.[51] In 1913, Danish physicist Niels Bohr postulated that electrons resided in quantized energy states, with their energies determined by the angular momentum of the electron’s orbit about the nucleus.
The electrons could move between those states, or orbits, by the emission or absorption of photons of specific frequencies. By means of these quantized orbits, he accurately explained the spectral lines of the hydrogen atom.[52] However, Bohr’s model failed to account for the relative intensities of the spectral lines and it was unsuccessful in explaining the spectra of more complex atoms.[51]
Chemical bonds between atoms were explained by Gilbert Newton Lewis, who in 1916 proposed that a covalent bond between two atoms is maintained by a pair of electrons shared between them.[53] Later, in 1927, Walter Heitler and Fritz London gave the full explanation of the electron-pair formation and chemical bonding in terms of quantum mechanics.[54]
In 1919, the American chemist Irving Langmuir elaborated on the Lewis’s static model of the atom and suggested that all electrons were distributed in successive “concentric (nearly) spherical shells, all of equal thickness”.[55] In turn, he divided the shells into a number of cells each of which contained one pair of electrons. With this model Langmuir was able to qualitatively explain the chemical properties of all elements in the periodic table,[54] which were known to largely repeat themselves according to the periodic law.[56]
